air pollution contamination of the air by noxious gases and minute particles of solid and liquid matter (particulates) in concentrations that endanger health. The major sources of air pollution are transportation engines, power and heat generation, industrial processes, and the burning of solid waste .

Sources of Air Pollution

The combustion of gasoline and other hydrocarbon fuels in automobiles , trucks, and jet airplanes produces several primary pollutants: nitrogen oxides, gaseous hydrocarbons, and carbon monoxide, as well as large quantities of particulates, chiefly lead. In the presence of sunlight, nitrogen oxides combine with hydrocarbons to form a secondary class of pollutants, the photochemical oxidants, among them ozone and the eye-stinging peroxyacetylnitrate (PAN). Nitrogen oxides also react with oxygen in the air to form nitrogen dioxide, a foul-smelling brown gas. In urban areas like Los Angeles where transportation is the main cause of air pollution, nitrogen dioxide tints the air, blending with other contaminants and the atmospheric water vapor to produce brown smog . Although the use of catalytic converters has reduced smog-producing compounds in motor vehicle exhaust emissions, recent studies have shown that in so doing the converters produce nitrous oxide, which contributes substantially to global warming .

In cities, air may be severely polluted not only by transportation but also by the burning of fossil fuels (oil and coal) in generating stations, factories, office buildings, and homes and by the incineration of garbage. The massive combustion produces tons of ash, soot, and other particulates responsible for the gray smog of cities like New York and Chicago, along with enormous quantities of sulfur oxides (which also may be result from burning coal and oil). These oxides rust iron, damage building stone, decompose nylon, tarnish silver, and kill plants. Air pollution from cities also affects rural areas for many miles downwind.

Every industrial process exhibits its own pattern of air pollution. Petroleum refineries are responsible for extensive hydrocarbon and particulate pollution. Iron and steel mills, metal smelters, pulp and paper mills, chemical plants, cement and asphalt plants—all discharge vast amounts of various particulates. Uninsulated high-voltage power lines ionize the adjacent air, forming ozone and other hazardous pollutants. Airborne pollutants from other sources include insecticides , herbicides , radioactive fallout , and dust from fertilizers, mining operations, and livestock feedlots.

Effects on Health and the Environment

Like photochemical pollutants, sulfur oxides contribute to the incidence of respiratory diseases. Acid rain , a form of precipitation that contains high levels of sulfuric or nitric acids, can contaminate drinking water and vegetation, damage aquatic life, and erode buildings. When a weather condition known as a temperature inversion prevents dispersal of smog, inhabitants of the area, especially children and the elderly and chronically ill, are warned to stay indoors and avoid physical stress. The dramatic and debilitating effects of severe air pollution episodes in cities throughout the world—such as the London smog of 1952 that resulted in 4,000 deaths—have alerted governments to the necessity for crisis procedures. Even everyday levels of air pollution may insidiously affect health and behavior. Indoor air pollution is a problem in developed countries, where efficient insulation keeps pollutants inside the structure. In less developed nations, the lack of running water and indoor sanitation can encourage respiratory infections. Carbon monoxide, for example, by driving oxygen out of the bloodstream, causes apathy, fatigue, headache, disorientation, and decreased muscular coordination and visual acuity.

Air pollution may possibly harm populations in ways so subtle or slow that they have not yet been detected. For that reason research is now under way to assess the long-term effects of chronic exposure to low levels of air pollution—what most people experience—as well as to determine how air pollutants interact with one another in the body and with physical factors such as nutrition , stress, alcohol, cigarette smoking , and common medicines. Another subject of investigation is the relation of air pollution to cancer , birth defects , and genetic mutations .

A recently discovered result of air pollution are seasonal "holes" in the ozone layer in the atmosphere above Antarctica and the Arctic, coupled with growing evidence of global ozone depletion. This can increase the amount of ultraviolet radiation reaching the earth, where it damages crops and plants and can lead to skin cancer and cataracts . This depletion has been caused largely by the emission of chlorofluorocarbons (CFCs) from refrigerators, air conditioners, and aerosols. The Montreal Protocol of 1987 required that developed nations signing the accord not exceed 1986 CFC levels. Several more meetings were held from 1990 to 1997 to adopt agreements to accelerate the phasing out of ozone-depleting substances.

Solutions to Air Pollution

To combat pollution in the United States, the Clean Air Act Amendments of 1970 gave the Environmental Protection Agency (EPA) the authority to establish and enforce air pollution standards and to set emission standards for new factories and extremely hazardous industrial pollutants. The states were required to meet "ambient air quality standards" by regulating the emissions of various pollutants from existing stationary sources, such as power plants and incinerators, in part by the installation of smokestack scrubbers, electrostatic precipitators, and other filters. Auto manufacturers were mandated to install exhaust controls or develop less polluting engines. The Clean Air Act, as amended in 1977, authorized the EPA to impose stricter pollution standards and higher penalties for failure to comply with air quality standards.

In 1990 when the act was reauthorized it required most cities to meet existing smog reduction regulations by the year 2005. The 1990 amendments also expanded the scope and strength of the regulations for controlling industrial pollution. The result has been limited progress in reducing the quantities of sulfur dioxide, carbon monoxide, nitrogen oxide, ozone, particulate matter, and lead in the air. The EPA also regulated hazardous air pollutants, which in 1992 included mercury, beryllium, asbestos, vinylchloride, benzene, radioactive substances, and inorganic arsenic.

The most satisfactory long-term solutions to air pollution may well be the elimination of fossil fuels and the ultimate replacement of the internal-combustion engine . To these ends efforts have begun in the United States, Japan, and Europe to develop alternative energy sources (see energy, sources of ), as well as different kinds of transportation engines, perhaps powered by electricity or steam. A system of pollution allowances based on trading emission rights has been established in the United States in an attempt to use the free market to reward pollution reductions, and the international sale of surplus emission rights is permitted under the Kyoto Protocol (see below). Other proposed solutions include raising electricity and gasoline rates to better reflect environmental costs and to discourage waste and inefficiency, and mechanical controls on coal-fired utility plants.

In 1992, 150 nations signed a treaty on global warming at the UN-sponsored summit on the environment in Rio de Janeiro. A UN Conference on Climate Change, held in Kyoto, Japan, in 1997, produced an international agreement to combat global warming by sharply reducing emissions of industrial gases. Although the United States abandoned the treaty in 2001, saying it was counter to U.S. interests, most other nations agreed that year on the details necessary to make the protocol a binding international treaty, and the necessary ratifications brought the treaty into force in 2005.

WATER POLLUTION

Industrial Pollution

In the United States industry is the greatest source of pollution, accounting for more than half the volume of all water pollution and for the most deadly pollutants. Some 370,000 manufacturing facilities use huge quantities of freshwater to carry away wastes of many kinds. The waste-bearing water, or effluent, is discharged into streams, lakes, or oceans, which in turn disperse the polluting substances. In its National Water Quality Inventory, reported to Congress in 1996, the U.S. Environmental Protection Agency concluded that approximately 40% of the nation's surveyed lakes, rivers, and estuaries were too polluted for such basic uses as drinking supply, fishing, and swimming. The pollutants include grit, asbestos , phosphates and nitrates , mercury , lead , caustic soda and other sodium compounds, sulfur and sulfuric acid , oils, and petrochemicals .

In addition, numerous manufacturing plants pour off undiluted corrosives, poisons, and other noxious byproducts. The construction industry discharges slurries of gypsum, cement, abrasives, metals, and poisonous solvents. Another pervasive group of contaminants entering food chains is the polychlorinated biphenyl (PCB) compounds, components of lubricants, plastic wrappers, and adhesives. In yet another instance of pollution, hot water discharged by factories and power plants causes so-called thermal pollution by increasing water temperatures. Such increases change the level of oxygen dissolved in a body of water, thereby disrupting the water's ecological balance, killing off some plant and animal species while encouraging the overgrowth of others.

Other Sources of Water Pollution

Towns and municipalities are also major sources of water pollution. In many public water systems, pollution exceeds safe levels. One reason for this is that much groundwater has been contaminated by wastes pumped underground for disposal or by seepage from surface water. When contamination reaches underground water tables, it is difficult to correct and spreads over wide areas. In addition, many U.S. communities discharge untreated or only partially treated sewage into the waterways, threatening the health of their own and neighboring populations.

Along with domestic wastes, sewage carries industrial contaminants and a growing tonnage of paper and plastic refuse (see solid waste ). Although thorough sewage treatment would destroy most disease-causing bacteria, the problem of the spread of viruses and viral illness remains. Additionally, most sewage treatment does not remove phosphorus compounds, contributed principally by detergents, which cause eutrophication of lakes and ponds. Excreted drugs and household chemicals also are not removed by present municipal treatment facilites, and can be recycled into the drinking water supply.

Rain drainage is another major polluting agent because it carries such substances as highway debris (including oil and chemicals from automobile exhausts), sediments from highway and building construction, and acids and radioactive wastes from mining operations into freshwater systems as well as into the ocean. Also transported by rain runoff and by irrigation return-flow are animal wastes from farms and feedlots, a widespread source of pollutants impairing rivers and streams, groundwater, and even some coastal waters. Antibiotics, hormones, and other chemicals used to raise livestock are components of such animal wastes. Pesticide and fertilizer residues from farms also contribute to water pollution via rain drainage.

Ocean Pollution

Large and small craft significantly pollute both inland and coastal waters by dumping their untreated sewage. Oil spilled accidentally or flushed from tankers and offshore rigs (900,000 metric tons annually) sullies beaches and smothers bird, fish, and plant life. In 1989 in one of the world's worst single instances of water pollution, the Exxon Valdez spilled 11 million gallons of oil in Prince William Sound, Alaska, causing great environmental destruction. In 1997, the 22 oil spills reported worldwide involved a total of 15 million gallons (57 million liters) of oil. In addition to its direct damage to wildlife, oil takes up fat-soluble poisons like DDT, allowing them to be concentrated in organisms that ingest the oil-contaminated water; thus such poisons enter the food chains leading to sea mammals and people (see ecology ).

Both DDT, which has been banned in the United States since 1972, and PCBs are manufactured in many parts of the world and are now widespread in the Atlantic and Pacific oceans. In addition, tarry oil residues are encountered throughout the Atlantic, as are styrofoam and other plastic rubbish. Plastic bits litter sections of the Pacific as far north as Amchitka Island near Alaska. Garbage, solid industrial wastes, and sludge formed in sewage treatment, all commonly dumped into oceans, are other marine pollutants found worldwide, especially along coastal areas.

Dangers of Water Pollution

Virtually all water pollutants are hazardous to humans as well as lesser species; sodium is implicated in cardiovascular disease, nitrates in blood disorders. Mercury and lead can cause nervous disorders. Some contaminants are carcinogens. DDT is toxic to humans and can alter chromosomes. PCBs cause liver and nerve damage, skin eruptions, vomiting, fever, diarrhea, and fetal abnormalities. Along many shores, shellfish can no longer be taken because of contamination by DDT, sewage, or industrial wastes.

Dysentery , salmonellosis , cryptosporidium , and hepatitis are among the maladies transmitted by sewage in drinking and bathing water. In the United States, beaches along both coasts, riverbanks, and lake shores have been ruined for bathers by industrial wastes, municipal sewage, and medical waste. Water pollution is an even greater problem in the Third World, where millions of people obtain water for drinking and sanitation from unprotected streams and ponds that are contaminated with human waste. This type of contamination has been estimated to cause more than 3 million deaths annually from diarrhea in Third World countries, most of them children.

Legislation and Control

The United States has enacted extensive federal legislation to fight water pollution. Laws include the Federal Water Pollution Control Act (1972), the Marine Protection, Research, and Sanctuaries Act (1972), the Safe Drinking Water Act (1974), and the Federal Insecticide, Fungicide, and Rodenticide Act, as amended in 1988. In the United States in 1996, nearly $10 billion was spent on water and wastewater treatment alone. International cooperation is being promoted by the Inter-Governmental Maritime Consultive Organization (IMCO), a UN agency. Limitation of ocean dumping was proposed at the 80-nation London Conference of 1972, and in the same year 12 European nations meeting in Oslo adopted rules to regulate dumping in the North Atlantic. An international ban on ocean dumping in 1988 set further restrictions.

Global warming

Global warming the gradual increase of the temperature of the earth's lower atmosphere as a result of the increase in greenhouse gases since the Industrial Revolution .

The temperature of the atmosphere near the earth's surface is warmed through a natural process called the greenhouse effect. Visible, shortwave light comes from the sun to the earth, passing unimpeded through a blanket of thermal, or greenhouse, gases composed largely of water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Infrared radiation reflects off the planet's surface toward space but does not easily pass through the thermal blanket. Some of it is trapped and reflected downward, keeping the planet at an average temperature suitable to life, about 60°F (16°C).